THE THERMODYNAMICS OF PHASE AND REACTION EQUILIBRIA

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The Thermodynamics Of Phase And Reaction Equilibria

Author : Ismail Tosun
ISBN : 9780444595027
Genre : Science
File Size : 35.78 MB
Format : PDF, ePub
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This book provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g. partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. It also presents numerical methods necessary for solving real-world problems as well the basic mathematics needed, facilitating its use as a self-study reference work. In the example problems requiring MATHCAD® for the solution, the results of the intermediate steps are given, enabling the reader to easily track mistakes and understand the order of magnitude of the various quantities involved. Clear layout, coherent and logical organization of the content, and presentation suitable for self-study Provides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients Includes up-to-date information, comprehensive in-depth content and current examples in each chapter Includes many well organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving Includes the mathematical background required for solving problems encountered in phase and reaction equilibria
Category: Science

The Thermodynamics Of Phase And Reaction Equilibria

Author : Ismail Tosun
ISBN : 9780444594976
Genre : Technology & Engineering
File Size : 85.36 MB
Format : PDF, Mobi
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This volume presents a sound foundation for understanding abstract concepts (physical properties such as fugacity, or chemical processes, such as distillation) of phase and reaction equilibria, and shows you how to apply these concepts to solve practical problems using numerous, clear examples. The book encourages the use of MATHCAD to write programs specific to each problem, enabling you to easily track mistakes and understand the order of magnitude of the various quantities involved. Provides guidelines in order to choose the 'best' equation of state suitable for the particular situation Includes up-to-date information, comprehensive in-depth content and current examples in each chapter Provides the right tools in order to and encourages you to use MATHCAD to write your own specific programs Includes many well organized problems (with solutions), which are extensions of the examples enabling conceptual understanding to quantitative/real problem solving Includes all mathematical background required for solving problems encountered in phase and reaction equilibria Provides a Solutions Manual (for instructors in pdf form) allowing the use of the book in advanced thermodynamic courses
Category: Technology & Engineering

The Thermodynamics Of Phase And Reaction Equilibria

Author : Ismail Tosun
ISBN : 1493302442
Genre : Science
File Size : 55.7 MB
Format : PDF, ePub
Download : 650
Read : 752

This book provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g. partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. It also presents numerical methods necessary for solving real-world problems as well the basic mathematics needed, facilitating its use as a self-study reference work. In the example problems requiring MATHCAD® for the solution, the results of the intermediate steps are given, enabling the reader to easily track mistakes and understand the order of magnitude of the various quantities involved. Clear layout, coherent and logical organization of the content, and presentation suitable for self-study Provides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients Includes up-to-date information, comprehensive in-depth content and current examples in each chapter Includes many well organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving Includes the mathematical background required for solving problems encountered in phase and reaction equilibria Provides an instructor's solutions manual
Category: Science

Phase Equilibria Phase Diagrams And Phase Transformations

Author : Mats Hillert
ISBN : 9781139465861
Genre : Technology & Engineering
File Size : 20.47 MB
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Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.
Category: Technology & Engineering

Phase Equilibria In Chemical Engineering

Author : Stanley M. Walas
ISBN : 9781483145082
Genre : Science
File Size : 54.3 MB
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Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics. Following material on basic thermodynamics and nonidealities in terms of fugacities and activities, individual chapters are devoted to equilibria primarily between pairs of phases. A few topics that do not fit into these categories and for which the state of the art is not yet developed quantitatively have been relegated to a separate chapter. The chapter on chemical equilibria is pertinent since many processes involve simultaneous chemical and phase equilibria. Also included are chapters on the evaluation of enthalpy and entropy changes of nonideal substances and mixtures, and on experimental methods. This book is intended as a reference and self-study as well as a textbook either for full courses in phase equilibria or as a supplement to related courses in the chemical engineering curriculum. Practicing engineers concerned with separation technology and process design also may find the book useful.
Category: Science

Classical And Geometrical Theory Of Chemical And Phase Thermodynamics

Author : Frank Weinhold
ISBN : 0470435054
Genre : Science
File Size : 67.94 MB
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Because it is grounded in math, chemical thermodynamics is often perceived as a difficult subject and many students are never fully comfortable with it. The first authoritative textbook presentation of equilibrium chemical and phase thermodynamics in a reformulated geometrical framework, Chemical and Phase Thermodynamics shows how this famously difficult subject can be accurately expressed with only elementary high-school geometry concepts. Featuring numerous suggestions for research-level extensions, this simplified alternative to standard calculus-based thermodynamics expositions is perfect for undergraduate and beginning graduate students as well as researchers.
Category: Science

Thermodynamics

Author : Ä°smail Tosun
ISBN : 9789814696951
Genre : Technology & Engineering
File Size : 40.57 MB
Format : PDF, Kindle
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This eminently readable introductory text provides a sound foundation to understand the abstract concepts used to express the laws of thermodynamics. The emphasis is on the fundamentals rather than spoon-feeding the subject matter. The concepts are explained with utmost clarity in simple and elegant language. It provides the background material needed for students to solve practical problems related to thermodynamics. Answers to all problems are provided.
Category: Technology & Engineering

Introduction To The Thermodynamics Of Materials Sixth Edition

Author : David R. Gaskell
ISBN : 9781498757010
Genre : Technology & Engineering
File Size : 76.97 MB
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Maintaining the substance that made Introduction to the Thermodynamic of Materials a perennial best seller for decades, this Sixth Edition is updated to reflect the broadening field of materials science and engineering. The new edition is reorganized into three major sections to align the book for practical coursework, with the first (Thermodynamic Principles) and second (Phase Equilibria) sections aimed at use in a one semester undergraduate course. The third section (Reactions and Transformations) can be used in other courses of the curriculum that deal with oxidation, energy, and phase transformations. The book is updated to include the role of work terms other than PV work (e.g., magnetic work) along with their attendant aspects of entropy, Maxwell equations, and the role of such applied fields on phase diagrams. There is also an increased emphasis on the thermodynamics of phase transformations and the Sixth Edition features an entirely new chapter 15 that links specific thermodynamic applications to the study of phase transformations. The book also features more than 50 new end of chapter problems and more than 50 new figures.
Category: Technology & Engineering

A Textbook Of Chemical Engineering Thermodynamics

Author : K. V. NARAYANAN
ISBN : 9788120347472
Genre : Technology & Engineering
File Size : 71.93 MB
Format : PDF
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Designed as an undergraduate-level textbook in Chemical Engineering, this student-friendly, thoroughly class-room tested book, now in its second edition, continues to provide an in-depth analysis of chemical engineering thermodynamics. The book has been so organized that it gives comprehensive coverage of basic concepts and applications of the laws of thermodynamics in the initial chapters, while the later chapters focus at length on important areas of study falling under the realm of chemical thermodynamics. The reader is thus introduced to a thorough analysis of the fundamental laws of thermodynamics as well as their applications to practical situations. This is followed by a detailed discussion on relationships among thermodynamic properties and an exhaustive treatment on the thermodynamic properties of solutions. The role of phase equilibrium thermodynamics in design, analysis, and operation of chemical separation methods is also deftly dealt with. Finally, the chemical reaction equilibria are skillfully explained. Besides numerous illustrations, the book contains over 200 worked examples, over 400 exercise problems (all with answers) and several objective-type questions, which enable students to gain an in-depth understanding of the concepts and theory discussed. The book will also be a useful text for students pursuing courses in chemical engineering-related branches such as polymer engineering, petroleum engineering, and safety and environmental engineering. New to This Edition • More Example Problems and Exercise Questions in each chapter • Updated section on Vapour–Liquid Equilibrium in Chapter 8 to highlight the significance of equations of state approach • GATE Questions up to 2012 with answers
Category: Technology & Engineering

Molecular Thermodynamics Of Fluid Phase Equilibria

Author : John M. Prausnitz
ISBN : 9780132440509
Genre : Science
File Size : 59.37 MB
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The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.
Category: Science