THE THERMODYNAMICS OF PHASE AND REACTION EQUILIBRIA

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The Thermodynamics Of Phase And Reaction Equilibria

Author : Ismail Tosun
ISBN : 9780444595027
Genre : Science
File Size : 53.95 MB
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This book provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g. partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. It also presents numerical methods necessary for solving real-world problems as well the basic mathematics needed, facilitating its use as a self-study reference work. In the example problems requiring MATHCAD® for the solution, the results of the intermediate steps are given, enabling the reader to easily track mistakes and understand the order of magnitude of the various quantities involved. Clear layout, coherent and logical organization of the content, and presentation suitable for self-study Provides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients Includes up-to-date information, comprehensive in-depth content and current examples in each chapter Includes many well organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving Includes the mathematical background required for solving problems encountered in phase and reaction equilibria
Category: Science

The Thermodynamics Of Phase And Reaction Equilibria

Author : Ismail Tosun
ISBN : 9780444594976
Genre : Technology & Engineering
File Size : 66.19 MB
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This volume presents a sound foundation for understanding abstract concepts (physical properties such as fugacity, or chemical processes, such as distillation) of phase and reaction equilibria, and shows you how to apply these concepts to solve practical problems using numerous, clear examples. The book encourages the use of MATHCAD to write programs specific to each problem, enabling you to easily track mistakes and understand the order of magnitude of the various quantities involved. Provides guidelines in order to choose the 'best' equation of state suitable for the particular situation Includes up-to-date information, comprehensive in-depth content and current examples in each chapter Provides the right tools in order to and encourages you to use MATHCAD to write your own specific programs Includes many well organized problems (with solutions), which are extensions of the examples enabling conceptual understanding to quantitative/real problem solving Includes all mathematical background required for solving problems encountered in phase and reaction equilibria Provides a Solutions Manual (for instructors in pdf form) allowing the use of the book in advanced thermodynamic courses
Category: Technology & Engineering

The Thermodynamics Of Phase And Reaction Equilibria

Author : Ismail Tosun
ISBN : 1493302442
Genre : Science
File Size : 89.67 MB
Format : PDF, Kindle
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This book provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g. partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. It also presents numerical methods necessary for solving real-world problems as well the basic mathematics needed, facilitating its use as a self-study reference work. In the example problems requiring MATHCAD® for the solution, the results of the intermediate steps are given, enabling the reader to easily track mistakes and understand the order of magnitude of the various quantities involved. Clear layout, coherent and logical organization of the content, and presentation suitable for self-study Provides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients Includes up-to-date information, comprehensive in-depth content and current examples in each chapter Includes many well organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving Includes the mathematical background required for solving problems encountered in phase and reaction equilibria Provides an instructor's solutions manual
Category: Science

Classical And Geometrical Theory Of Chemical And Phase Thermodynamics

Author : Frank Weinhold
ISBN : 0470435054
Genre : Science
File Size : 73.96 MB
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Because it is grounded in math, chemical thermodynamics is often perceived as a difficult subject and many students are never fully comfortable with it. The first authoritative textbook presentation of equilibrium chemical and phase thermodynamics in a reformulated geometrical framework, Chemical and Phase Thermodynamics shows how this famously difficult subject can be accurately expressed with only elementary high-school geometry concepts. Featuring numerous suggestions for research-level extensions, this simplified alternative to standard calculus-based thermodynamics expositions is perfect for undergraduate and beginning graduate students as well as researchers.
Category: Science

Phase Equilibria Phase Diagrams And Phase Transformations

Author : Mats Hillert
ISBN : 9781139465861
Genre : Technology & Engineering
File Size : 26.20 MB
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Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.
Category: Technology & Engineering

Thermodynamics

Author : Ä°smail Tosun
ISBN : 9789814696951
Genre : Technology & Engineering
File Size : 34.32 MB
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This eminently readable introductory text provides a sound foundation to understand the abstract concepts used to express the laws of thermodynamics. The emphasis is on the fundamentals rather than spoon-feeding the subject matter. The concepts are explained with utmost clarity in simple and elegant language. It provides the background material needed for students to solve practical problems related to thermodynamics. Answers to all problems are provided.
Category: Technology & Engineering

Phase Equilibria In Chemical Engineering

Author : Stanley M. Walas
ISBN : 9781483145082
Genre : Science
File Size : 59.39 MB
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Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics. Following material on basic thermodynamics and nonidealities in terms of fugacities and activities, individual chapters are devoted to equilibria primarily between pairs of phases. A few topics that do not fit into these categories and for which the state of the art is not yet developed quantitatively have been relegated to a separate chapter. The chapter on chemical equilibria is pertinent since many processes involve simultaneous chemical and phase equilibria. Also included are chapters on the evaluation of enthalpy and entropy changes of nonideal substances and mixtures, and on experimental methods. This book is intended as a reference and self-study as well as a textbook either for full courses in phase equilibria or as a supplement to related courses in the chemical engineering curriculum. Practicing engineers concerned with separation technology and process design also may find the book useful.
Category: Science

Chemical Engineering Thermodynamics

Author : Pradeep Ahuja
ISBN : 9788120336377
Genre : Science
File Size : 44.89 MB
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This book offers a full account of thermodynamic systems in chemical engineering. It provides a solid understanding of the basic concepts of the laws of thermodynamics as well as their applications with a thorough discussion of phase and chemical reaction equilibria. At the outset the text explains the various key terms of thermodynamics with suitable examples and then thoroughly deals with the virial and cubic equations of state by showing the P-V-T (pressure, molar volume and temperature) relation of fluids. It elaborates on the first and second laws of thermodynamics and their applications with the help of numerous engineering examples. The text further discusses the concepts of exergy, standard property changes of chemical reactions, thermodynamic property relations and fugacity. The book also includes detailed discussions on residual and excess properties of mixtures, various activity coefficient models, local composition models, and group contribution methods. In addition, the text focuses on vapour-liquid and other phase equilibrium calculations, and analyzes chemical reaction equilibria and adiabatic reaction temperature for systems with complete and incomplete conversion of reactants. key Features  Includes a large number of fully worked-out examples to help students master the concepts discussed.  Provides well-graded problems with answers at the end of each chapter to test and foster students’ conceptual understanding of the subject. The total number of solved examples and end-chapter exercises in the book are over 600.  Contains chapter summaries that review the major concepts covered. The book is primarily designed for the undergraduate students of chemical engineering and its related disciplines such as petroleum engineering and polymer engineering. It can also be useful to professionals. The Solution Manual containing the complete worked-out solutions to chapter-end exercises and problems is available for instructors.
Category: Science

Molecular Thermodynamics Of Fluid Phase Equilibria

Author : John M. Prausnitz
ISBN : 9780132440509
Genre : Science
File Size : 29.8 MB
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The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.
Category: Science

Phase Equilibria

Author : Arnold Reisman
ISBN : 9781483265841
Genre : Science
File Size : 26.70 MB
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Phase Equilibria: Basic Principles, Applications, Experimental Techniques presents an analytical treatment in the study of the theories and principles of phase equilibria. The book is organized to afford a deep and thorough understanding of such subjects as the method of species model systems; condensed phase-vapor phase equilibria and vapor transport reactions; zone refining techniques; and nonstoichiometry. Physicists, physical chemists, engineers, and materials scientists will find the book a good reference material.
Category: Science