MOLECULAR THERMODYNAMICS OF ELECTROLYTE SOLUTIONS

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Molecular Thermodynamics Of Electrolyte Solutions

Author : Lloyd L. Lee
ISBN : 9789812814180
Genre : Science
File Size : 85.81 MB
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The introductory textbook provides an update on electrolyte thermodynamics with a molecular perspective. It is eminently suited as an introduction to the solution thermodynamics of ionic mixtures at the undergraduate and graduate level. It is also invaluable for the understanding and design in the engineering of natural gas treating and adsorption refrigeration with electrolytes.
Category: Science

Molecular Thermodynamics Of Fluid Phase Equilibria

Author : John M. Prausnitz
ISBN : 9780132440509
Genre : Science
File Size : 43.34 MB
Format : PDF
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The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.
Category: Science

Molecular Thermodynamics Of Nonideal Fluids

Author : Lloyd L. Lee
ISBN : 9781483102115
Genre : Science
File Size : 35.72 MB
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Molecular Thermodynamics of Nonideal Fluids serves as an introductory presentation for engineers to the concepts and principles behind and the advances in molecular thermodynamics of nonideal fluids. The book covers related topics such as the laws of thermodynamics; entropy; its ensembles; the different properties of the ideal gas; and the structure of liquids. Also covered in the book are topics such as integral equation theories; theories for polar fluids; solution thermodynamics; and molecular dynamics. The text is recommended for engineers who would like to be familiarized with the concepts of molecular thermodynamics in their field, as well as physicists who would like to teach engineers the importance of molecular thermodynamics in the field of engineering.
Category: Science

Molecular Thermodynamics Of Complex Systems

Author : Xiaohua Lu
ISBN : 9783540691167
Genre : Science
File Size : 26.90 MB
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With the development of science and technology,more and more complex materials such as porous materials, ion liquid, liquid crystals, thin ?lms and colloids etc. are being developed in laboratories. However, it is dif?cult to prepare these advanced materials and use them on a large scale without some experience. Therefore, mo- cular thermodynamics, a method that laid emphasis on correlating and interpreting the thermodynamic properties of a variety of ?uids in the past, has been recently employed to study the equilibrium properties of complex materials and establish thermodynamic models to analyse the evolution process of their components, - crostructures and functions during the preparation process. In this volume, some important progress in this ?eld, from fundamental aspects to practical applications, is reviewed. In the ?rst chapter of this volume, Prof. Jianzhong Wu presents the application of Density Functional theory (DFT) for the study of the structure and thermodynamic properties of both bulk and inhomogeneous ?uids. This chapter presents a tut- ial overview of the basic concepts of DFT for classical systems, the mathematical relations linking the microstructure and correlation functions to measurable th- modynamic quantities, and the connections of DFT with conventional liquid-state theories. While for pedagogythe discussion is limited to one-componentsimple - ids, similar ideas and concepts are directly applicable to mixtures and polymeric systems of practical concern. This chapter also covers a few theoretical approaches to formulate the thermodynamic functional.
Category: Science

Classical Thermodynamics Of Non Electrolyte Solutions

Author : H. C. Van Ness
ISBN : 9781483225470
Genre : Science
File Size : 29.45 MB
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Classical Thermodynamics of Non-Electrolyte Solutions covers the historical development of classical thermodynamics that concerns the properties of vapor and liquid solutions of non-electrolytes. Classical thermodynamics is a network of equations, developed through the formal logic of mathematics from a very few fundamental postulates and leading to a great variety of useful deductions. This book is composed of seven chapters and begins with discussions on the fundamentals of thermodynamics and the thermodynamic properties of fluids. The succeeding chapter presents the equations of state for the calculation of the thermodynamic behavior of constant-composition fluids, both liquid and gaseous. These topics are followed by surveys of the mixing of pure materials to form a solution under conditions of constant temperature and pressure. The discussion then shifts to general equations for calculation of partial molal properties of homogeneous binary systems. The last chapter considers the approach to equilibrium of systems within which composition changes are brought about either by mass transfer between phases or by chemical reaction within a phase, or by both.
Category: Science

Statistical Thermodynamics

Author : M. C. Gupta
ISBN : 8122410669
Genre : Thermodynamics
File Size : 86.45 MB
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This Is An Introductory Book Which Explains The Foundations Of The Subject And Its Application. It Is Intended Primarily For Graduate Students But May Provide Useful Information And Reading To Science And Engineering Students At All Levels. It Assumes That Readers Have Knowledge Of Basic Thermodynamics And Quantum Mechanics. With This, The Theory Has Been Developed In A Simple, Logical And Understandable Way. Some Applications Of Statistical Thermodynamics Have Been Described In Detail With Illustrative Solved Examples.There Are Two Basic Approaches In Statistical Mechanics; One Based On The Study Of Independent Particles In An Isolated System And The Other Based On The Concept Of Ensembles. In This Book Attempt Has Been Made To Take Advantage Of Both Approaches. While The Fundamental Concepts Have Been Developed By First Approach, Concept Of Ensembles Have Been Included To Bring Out The Importance Of This Concept In The Application Of Statistical Thermodynamics To Chemical Systems Where Interparticle Interactions Become Important.Part I Of The Book Deals With The Background Concepts, Fundamentals In Mathematics, Classical Mechanics, Quantum Mechanics And Thermodynamics Which Are Essential For Statistical Mechanics. Part Ii Covers Formalism Of Statistical Mechanism And Its Relation To Thermodynamics As Well As The Statistical Mechanics Of Ensembles, Quantum Statistics And Fluctuations. Part Iii Includes Chapters On The Applications Of The Formalism To Real Laboratory Chemical Systems. In This Part Additions Such As Imperfect Gases, Equilibrium Isotope And Kinetic Isotope Effects And Reactions At The Surfaces Have Been Made, In This Edition. Part Iv Is Also An Addition Which Covers Quantum Systems Such As Ideal Fermi Gas (Free Electrons In Metals), Photon Gas And Ideal Bose Gas (Helium Gas).
Category: Thermodynamics

Molecular Thermodynamics Of Fluid Phase Equilibria

Author : J. M. Prausnitz
ISBN : UOM:39015000993983
Genre : Science
File Size : 20.95 MB
Format : PDF, Kindle
Download : 517
Read : 753

97774-4 The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics ofFluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and oth
Category: Science